The large optical bandgap (∼4.6 eV) and high Tg (∼277 °C) enable the alicyclic polyimide film to deliver a discharged energy density of ∼1.8 J/cm 3 at 150 °C with an
As electronic components, dielectric capacitors have received extensive investigation from researchers due to their ability to release and store charges [1,2,3].Dielectric
In recent years, researchers have been striving to achieve ultra-high energy storage performance, such as large recoverable energy storage density (W re), high energy storage efficiency (η) and long service life.However, the requirements for working in a wide temperature range of the film capacitors are also very important in many application fields,
Capacitors based on dielectric materials offer distinct advantages in power density when compared to other energy storage methods such as batteries and supercapacitors, especially in scenarios requiring rapid charge and discharge [1], [2].However, their relatively limited energy capacity has constrained their applications in integrated electrical systems,
Here we report record-high electrostatic energy storage density (ESD) and power density, to our knowledge, in HfO2–ZrO2-based thin film microcapacitors integrated into
Recently, dielectric materials with high energy-storage densities have attracted enormous interests due to their potential application within capacitors for modern electronics and electrical power systems [1, 2].As the increase of requirements for compact electronics, the capacitor with high energy-storage density has been extensively used in electric vehicles,
In this work, we studied the dielectric properties, electric polarization, and energy density of PMMA/2D Mica nanocomposite capacitors where stratified 2D nanofillers are interfaced between the multiple layers of
At x = 0.32, the film demonstrates exceptional energy storage properties at ambient temperature, boasting an energy storage density of 103 J cm −3 and energy storage efficiency of 79 % under an electric field of 4143 kV cm −1. Notably, the film capacitor exhibits outstanding high-temperature energy storage capabilities and remarkable stability over a wide temperature
The recoverable energy storage density of freestanding PbZr 0.52 Ti 0.48 O 3 thin films increases from 99.7 J cm −3 in the strain (defect) -free state to 349.6 J cm −3, marking a significant increase of 251%. The collective
Capacitors exhibit exceptional power density, a vast operational temperature range, remarkable reliability, lightweight construction, and high efficiency, making them
Electrostatic capacitors can enable ultrafast energy storage and release, but advances in energy density and efficiency need to be made. Here, by doping equimolar Zr, Hf and Sn into Bi4Ti3O12 thin
In particular, ultra-high recoverable energy storage density (Wrec ∼ 75.4 J/cm³) and efficiency (η ∼ 88%) are achieved simultaneously in ZrO2 film-based (470 nm thick) capacitors, rivaling
Remarkably, our Bi 0.5 Na 0.5 TiO 3 -based high-entropy thin film capacitor not only showcases industry-leading energy storage properties at room temperature, with a recoverable energy
Hence, enhancing the energy storage density (U) of dielectric capacitors has been the critical issue for the past decade. [23][24][25][26][27][28][29] [30] [31][32][33] Take polymer dielectric
In the research field of energy storage dielectrics, the "responsivity" parameter, defined as the recyclable/recoverable energy density per unit electric field, has become critically important for a comprehensive evaluation of the energy storage capability of a dielectric. In this work, high recyclable energy density and responsivity, i.e., <i>W</i><sub>rec</sub> = 161.1
In this work, we demonstrate that the high-energy storage density (114.49 J cm −3) can be achieved in 0.85BaTiO 3 -0.15Bi (Mg 0.5 Zr 0.5)O 3 (BT-BMZ) films by optimized
High energy storage density with low-energy loss polymer films are essential for high-performance electric devices. Polymer-based materials for achieving high energy density film capacitors. Progress in Polymer Science, Volume 97, 2019, Article 101143. Benhui Fan, ,
The recoverable energy-storage density (U Re) is 12.30 J/cm 3. The results also reveal that rapid thermal processing (RTP) enhances the ferroelectric and energy storage properties of the film by comparison with unannealed, and ferroelectric and energy storage properties exhibit a strong voltage dependence.
Interestingly, the Eb under positive field is enhanced significantly and an ultrahigh energy density up to 307 J/cm3 with a high efficiency of 89% is realized and the enhanced Eb may be related to the modulation of local electric field and redistribution of oxygen vacancies at the STO/LSMO interface. Solid-state dielectric film capacitors with high-energy-storage density will further
Especially in the 1.5% Mn-BMT0.7 film capacitor, an ultrahigh energy storage density of 124 J cm⁻³ and an outstanding efficiency of 77% are obtained, which is one of the best energy storage
However, the energy storage density of electrostatic capacitors is much lower than that of other electrochemical energy storage devices due to the relatively low dielectric constant of the dielectric materials. This may require a larger volume of capacitors to meet capacity requirements [2].
The energy storage density (ESD) of the capacitor reaches 28.94 J cm⁻³, and the energy storage efficiency of the capacitor is up to 91.3% under an applied electric field of 3.5 MV cm⁻¹.
The recoverable energy storage density of freestanding PbZr 0.52 Ti 0.48 O 3 thin films increases from 99.7 J cm −3 in the strain (defect) Thin film capacitors have garnered extensive attention and research due to
The ubiquitous, rising demand for energy storage devices with ultra-high storage capacity and efficiency has drawn tremendous research interest in developing energy storage devices. Dielectric polymers are one of
At E < 500 kV/cm, we demonstrated a remarkable energy density enhancement of more than 100% compared to the non-imprinted PMN–33PT thin film while
Especially in the 1.5% Mn-BMT0.7 film capacitor, an ultrahigh energy storage density of 124 J cm⁻³ and an outstanding efficiency of 77% are obtained, which is one of the best energy storage
In addition, the film capacitors exhibit good thermal stability over the temperature range of −100 to 225 °C and fatigue properties (10 6 cycles). Importantly, the energy storage density reaches 62.3 J cm −3 at 225 °C, and the energy storage efficiency is as high as ∼81%. Our results show that the optimal BT-BMZ film achieved by tuning
Ferroelectric thin film capacitors have attracted increasing attention because of their high energy storage density and fast charge-discharge speed, but less attention has been paid to the realization of flexible capacitors for wearable electronics and power systems. Especially in the 1.5% Mn-BMT 0.7 film capacitor, an ultrahigh energy
However, their relatively low permittivity result in low energy storage density of polymer film capacitors. For example, biaxially oriented polypropylene (BOPP), one of the most representative dielectrics for commercial polymer films, has a permittivity and energy storage density limited to below 2.25 and 5 J cm −3, respectively [ 4 ].
Extensive efforts have been devoted to develop miniaturized and lightweight dielectric film capacitors with high energy density and high stability [5, 6]. Nevertheless, the bottleneck of the energy storage density in BT-based RFE is the inferior polarization as the spontaneous polarization of BT is only 26 μC/cm 3 [12].
The strains result in the increase in the energy storage density of the BZT film up to 66.9 J/cm³ with an energy storage efficiency of 73.2% at room temperature, which is 2.2 times as high as
Lead-free thin film capacitors, simultaneously possessing a large energy storage density, ultrahigh efficiency and an extra wide working temperature range, are desirable in applications. In this work, A2Bi4Ti5O18 (A
Different from traditional dielectric capacitors that only rely on polarization charges for energy storage, this work designs an intermediate band ferroelectric Bi 2 W 0.94 Ni 0.06 O 6-δ (BWNO) flexible film capacitor with strong photoelectric effect for collaborative energy storage by photoelectrons and polarization charges. Intermediate band as a springboard
The energy storage density of the metadielectric film capacitors can achieve to 85 joules per cubic centimeter with energy efficiency exceeding 81% in the temperature range
The ability to work at ultralow (−90 °C) or ultrahigh (200 °C) temperature with superior energy storage properties is essential for dielectric capacitors to operate in harsh environments. Here, we realized an ultrahigh recoverable energy
The discharge energy density (U d) of a dielectric capacitor is equal to the integral U d = ∫ E d P, where P represents polarization and E is the applied electric field. 8 Compared with batteries and electrochemical capacitors, the relatively low energy density of dielectric capacitors (2 J/cm 3 for commercial polymer or ceramic capacitors) has become a
Energy density, Ue = ½ Kε 0 E b 2, is used as a figure-of-merit for assessing a dielectric film, where high dielectric strength (E b) and high dielectric constant (K) are desirable addition to the energy density, dielectric loss is another critical parameter since dielectric loss causes Joule heating of capacitors at higher frequencies, which can lead to failure of
The energy storage parameters of a nonlinear dielectric capacitor can be obtained from the polarization-electric field (P–E) hysteresis loop by the following equations: (1) (2) (3) U Loss = U T –U Rec (4) η = [U Rec /(U Rec + U Loss)] × 100% Here, U T, U Rec, U Loss, and η represent, respectively, the total stored energy density, recoverable energy density,
Since the energy storage density (U) of linear dielectrics is strongly dependent on ε r and applied electric field (E), as guided by U = ε 0 ε r E 2 /2 [11, 22], many researchers are striving to increase ε r and/or electric breakdown strength (E b) to further improve the energy density of PE-based capacitors [[15], [16], [17], [18]].
The energy storage density of the metadielectric film capacitors can achieve to 85 joules per cubic centimeter with energy efficiency exceeding 81% in the temperature range from 25 °C to 400 °C.
Capacitors exhibit exceptional power density, a vast operational temperature range, remarkable reliability, lightweight construction, and high efficiency, making them extensively utilized in the realm of energy storage. There exist two primary categories of energy storage capacitors: dielectric capacitors and supercapacitors.
Pan, H. et al. Giant energy density and high efficiency achieved in bismuth ferrite-based film capacitors via domain engineering. Nat. Commun. 9, 1813 (2018). Chen, X. et al. Giant energy storage density in lead-free dielectric thin films deposited on Si wafers with an artificial dead-layer. Nano Energy 78, 105390 (2020).
Thin film capacitors have garnered extensive attention and research due to their robust breakdown strength, miniaturization, and substantial energy storage density. Ferroelectric oxide thin film capacitors are widely employed in commercial capacitors.
Here we report record-high electrostatic energy storage density (ESD) and power density, to our knowledge, in HfO 2 –ZrO 2 -based thin film microcapacitors integrated into silicon, through a three-pronged approach.
A record-high energy density of ∼4.9 J/cm 3 with η > 95 % is obtained at 150 °C. Stable cyclability over 100,000 cycles under 400 MV/m at 150 °C is achieved. Film capacitors based on polymer dielectrics face substantial challenges in meeting the requirements of developing harsh environment (≥150 °C) applications.
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