
A sodium–sulfur (NaS) battery is a type of that uses liquid and liquid . This type of battery has a similar to , and is fabricated from inexpensive and low-toxicity materials. Due to the high operating temperature required (usually between 300 and 350 °C), as well as the highly reactive nature of sodium and The charge and discharge process can be described by the chemical equation, 2Na + 4S ↔ Na 2 S 4. [3] [pdf]
The typical sodium sulfur battery consists of a negative molten sodium electrode and an also molten sulfur positive electrode. The two are separated by a layer of beta alumina ceramic electrolyte that primarily only allows sodium ions through. The charge and discharge process can be described by the chemical equation, 2Na + 4S ↔ Na 2 S 4.
Figure 1. Battery Structure The typical sodium sulfur battery consists of a negative molten sodium electrode and an also molten sulfur positive electrode. The two are separated by a layer of beta alumina ceramic electrolyte that primarily only allows sodium ions through.
The sodium-sulfur battery (Na–S) combines a negative electrode of molten sodium, liquid sulfur at the positive electrode, and β-alumina, a sodium-ion conductor, as the electrolyte to produce 2 V at 320 °C. This secondary battery has been used for buffering solar and wind energy to mitigate electric grid fluctuations.
In sodium-sulfur batteries, the electrolyte is in solid state but both electrodes are in molten states—i.e., molten sodium and molten sulfur as electrodes.
made of molten sodium (Na). The electrodes are separated by a solid ceramic, sodium beta alumina, which al o serves as the electrolyte. This ceramic allows only positively charged sodium ions to pass through. The battery temperature is kept between 300° C and 360° C to keep the electrodes in a molten state, i.e. independent heaters ar
Utility-scale sodium–sulfur batteries are manufactured by only one company, NGK Insulators Limited (Nagoya, Japan), which currently has an annual production capacity of 90 MW . The sodium sulfur battery is a high-temperature battery. It operates at 300°C and utilizes a solid electrolyte, making it unique among the common secondary cells.
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